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航天装备关键部件须经受高温高载及复杂环境的严苛考验,其热端部件的可靠服役性能一直是航天领域研究的热点问题之一。超高温高速气流冲刷、高能武器威胁造成的烧蚀等极端条件下,热防护涂层须具备稳定的高温服役能力。近年来,高熵材料凭借优异的机械性能、热稳定性和化学稳定性,备受航天材料领域关注。针对高超音速飞行器在长航时飞行中对典型结构件的耐烧蚀需求,分析了耐烧蚀高熵涂层设计、制备与评估进展;重点分析了多组元高熵材料的组分优选策略和热防护涂层的先进制备工艺,并探讨了其性能调控机制,为高性能耐烧蚀高熵涂层的制备与性能提升提供了参考。
Abstract:The reliable service performance of hot-end components has long been a research focus in the aerospace field, as key components of aerospace equipment are subjected to rigorous tests under complex conditions involving high thermal and loads. Under extreme enviroments, such as high-thermal and high-speed gas flow erosion, and ablation caused by high-energy weapons, thermal protective coatings are required to maintain stable high-thermal service capabilities. In recent years, high-entropy materials, characterized by excellent mechanical properties, thermal and chemical stabilities, have attracted significant attention in the aerospace material field. Accordingly, the design, preparation, and evaluation progress of ablation-resistant high-entropy coatings were reviewed to address the need for ablation-resistant components of hypersonic vehicles in long-duration flights. The optimization strategies for multi-component high-entropy materials and advanced preparation processes for thermal protective coatings were analyzed, and the performance control machanisms were explored, providing support for the preparation and performance enhancement of high-performance ablation-resistant high-entropy coatings.
[1]ZHANG H, HE Y Z, PAN Y, et al. Synthesis and characterization of NiCoFeCrAl3high entropy alloy coating by laser cladding[J].Advanced Materials Research,2010,97-101:1408-1411.
[2]AKRAMI S, EDALATI P, FUJI M, et al.High-entropy ceramics:review of principles, production and applications[J]. Materials Science and Engineering:R-reports,2021,146:100644.
[3]GOSSETT E,TOHER C,OSES C,et al.AFLOW-ML:a RESTful API for machine-learning predictions of materials properties[J]. Computational Materials Science,2018,152:134-145.
[4]CHANG H Q,LU H,WANG H B,et al.Hardness-strength-toughness synergy of(NbMoTaW)C through TiC-TiO2dual-phase engineering[J].Journal of Materials Science&Technology,2026,255:96-107.
[5]LI C Y,GAO R N,OUYANG H B,et al.Hierarchical porous(Ta0.2Nb0.2Ti0.2Zr0.2Hf0.2)C high-entropy ceramics prepared by a self-foaming method for thermal insulation[J].Journal of Advanced Ceramics,2024,13(7):956-966.
[6]YUAN X J,QIU H F,ZENG F Q,et al.Microstructural evolution and mechanical properties of Inconel 625 superalloy fabricated by pulsed microplasma rapid additive manufacturing[J]. Journal of Manufacturing Processes,2022,77:63-74.
[7]汪刘应,王汉功.多功能微弧等离子喷涂技术与应用[M].北京:科学出版社,2010:1-2.
[8]查柏林,王汉功,袁晓静.超音速火焰喷涂技术及应用[M].北京:国防工业出版社,2013:2-8.
[9]WEN Z H,TANG Z Y,LIU Y W,et al.Ultrastrong and high thermal insulating porous highentropy ceramics up to 2 000℃[J].Advanced Materials,2024,36(14):2311870.
[10]ZHOU Y J, ZHANG Y, WANG Y L, et al.Microstructure and compressive properties of multicomponent Alx(TiVCrMnFeCoNiCu)100-xhigh-entropy alloys[J]. Materials Science and Engineering:A,2007,454:260-265.
[11]LUO W P,YUAN X J,ZHANG Z,et al.Effect of volumetric energy density on the mechanical properties and corrosion resistance of laser-additivemanufactured AlCoCrFeNi2.1high-entropy alloys[J].Journal of Alloys and Compounds, 2025, 1010:178032.
[12]ROST C M,SACHET E,BORMAN T,et al.Entropy-stabilized oxides[J].Nature Communications,2015,6:8485.
[13]REN J N,KUMKALE V Y,HOU H,et al.A review of high entropy materials with their unique applications[J]. Advanced Composites and Hybrid Materials,2025,8(2):195.
[14]余圣,刘家言,李龙丰,等.MoNbVTax系难熔高熵合金的高温氧化行为与机理[J].特种铸造及有色合金,2024,44(2):240-244.YU S,LIU J Y,LI L F,et al.High temperature oxidation behavior and mechanism of MoNbVTaxrefractory high entropy alloy[J].Special Casting&Nonferrous Alloys,2024,44(2),240-244.
[15]李天昕,王书道,卢一平,等.高熵合金材料研究进展与展望[J].中国工程科学,2023,25(3):170-181.LI T X,WANG S D,LU Y P,et al.Research progress and prospect of high-entropy alloy materials[J].Strategic Study of CAE,2023,25(3):170-181.
[16]MISHRA S, MAITI S, RAI B. Computational property predictions of Ta-Nb-Hf-Zr high-entropy alloys[J].Scientific Reports,2021,11(1):4815.
[17]WEI W J,HONG Y,SHI X L,et al.Enhanced irradiation stability of MOSFET devices realized by improving nucleus density of CrxNbMoTaW generated by lattice shrinkage[J].Materials Today Physics,2025,50:101639.
[18]SHITTU J,RIETEMA C J,JUHASZ M,et al.Microstructural, phase, and thermophysical stability of CrMoNbV refractory multi-principal element alloys[J]. Journal of Alloys and Compounds, 2024,977:173349.
[19]LI Z M, TASAN C C, SPRINGER H, et al.Interstitial atoms enable joint twinning and transformation induced plasticity in strong and ductile highentropy alloys[J]. Scientific Reports, 2017, 7(1):40704.
[20]ZHOU Y D, SHI T, LI J, et al. Element-dependent evolution of chemical short-range ordering tendency of NiCoFeCrMn under irradiation[J]. International Journal of Plasticity,2023,171:103768.
[21]PAVEL I, ELENA I, ALEKSANDR N, et al.Preparation of(Ti,Zr,Hf,Nb,Ta)C high-entropy carbide ceramics through carbosilicothermic reduction of oxides[J]. Journal of the European Ceramic Society,2021,41(14):6934-6942.
[22]ZHANG P X, YE L, CHEN F H, et al. Stability, mechanical, and thermodynamic behaviors of(TiZrHfTaM)C(M=Nb, Mo, W, V, Cr)highentropy carbide ceramics[J]. Journal of Alloys and Compounds,2022,903:163868.
[23]QI W,CHEN B,YANG X,et al.Phase stability,mechanical and thermodynamic properties of(Hf,Zr,Ta,M)B2(M=Nb,Ti,Cr,W)quaternary highentropy diboride ceramics via first-principles calculations[J]. Ceramics International, 2023, 49(20):33255-33264.
[24]KRETSCHMER A, MAYRHOFER P H. Hightemperature oxidation resistance of sputtered(Al,Cr,Nb,Ta,Ti,Si)N coatings[J].Journal of Alloys and Compounds,2025,1010:176912.
[25]吕莎莎,祖宇飞,陈国清,等.陶瓷颗粒增强Cr0.5MoNbWTi难熔高熵合金复合材料的制备及其力学性能[J].无机材料学报,2021,36(4):386-392.LYU S S,ZU Y F,CHEN G Q,et al.Preparation and mechanical property of the ceramic-reinforced Cr0.5MoNbWTi refractory high-entropy alloy matrix composites[J]. Journal of Inorganic Materials,2021,36(4):386-392.
[26]FAHRENHOLTZ W G,HILMAS G E,TALMY I G, et al. Refractory diborides of zirconium and hafnium[J].Journal of the American Ceramic Society,2007,90(5):1347-1364.
[27]邵亚云.真空热压烧结制备CuCrFeMnNi高熵合金的退火软化行为[J].特种铸造及有色合金,2024,44(7):935-939.SHAO Y Y. Annealing softening behavior of CuCrFeMnNi high-entropy alloy via vacuum hotpressing sintering[J]. Special Casting&Nonferrous Alloys,2024,44(7):935-939.
[28]GUO Q W, HOU H, WANG K L, et al. Coalescence of Al0.3CoCrFeNi polycrystalline high-entropy alloy in hot-pressed sintering:a molecular dynamics and phase-field study[J]. NPJ Computational Materials,2023,9:185.
[29]SMITH S M,FAHRENHOLTZ W G,HILMAS G E. Pressureless sintering of high-entropy boride ceramics[J]. Journal of the European Ceramic Society,2023,43(12):5168-5173.
[30]耿畅,李玉,李琳琳,等.无压两步烧结法制备超细晶(Ce0.2Nd0.2Sm0.2Gd0.2Y0.2)2Zr2O7高熵陶瓷[J].硅酸盐学报,2024,52(9):2915-2924.GENG C, LI Y, LI L L, et al. Preparation of ultrafine-grained(Ce0.2Nd0.2Sm0.2Gd0.2Y0.2)2Zr2O7highentropy ceramics via pressureless two-step sintering[J].Journal of the Chinese Ceramic Society,2024,52(9):2915-2924.
[31]郭凌翔,唐颖,黄世伟,等.C/C复合材料高熵氧化物涂层抗烧蚀性能[J].无机材料学报,2024,(1):61-70.GUO L X, TANG Y, HUANG S W, et al.Ablation resistance of high-entropy oxide coatings on C/C composites[J].Journal of Inorganic Materials,2024,(1):61-70.
[32]MU G Y, LIU Y B, TIAN X C, et al. Study on the ablation resistance of ZrB2-SiC-LaSi2coating prepared on the C/C composites[J].Corrosion Science,2024,227:111697.
[33]ZHANG B,MU W D,CAI Y.A novel strategy to regulate the precipitation-strengthened high-entropy alloy fabricated by laser directed energy deposition[J]. Materials Characterization, 2024, 215:114191.
[34]LIU M, XU L, LI Z, et al. Microstructure and wear properties of WMoNbTaVAl2O3high entropy alloy prepared by spark plasma sintering[J]. Rare Metal Materials and Engineering, 2024, 53(5):1236-1244.
[35]HUANG Z J,CHEN J P,TIAN Y,et al.Highentropy boride-carbide based composite prepared by reactive spark plasma sintering[J]. Journal of the European Ceramic Society, 2024, 44(8):5211-5215.
[36]靳亮,王德,王耀辉,等.热防护材料烧蚀性能测试方法研究[J].固体火箭技术,2018,41(2):245-250.JIN L,WANG D,WANG Y H,et al.Research on test method for ablation properties of ablative materials[J]. Journal of Solid Rocket Technology,2018,41(2):245-250.
[37]张睿,祝文祥,张澳,等.烧蚀型热防护系统概率设计与可靠性评估方法研究[J].计算力学学报,2024,41(4):762-768.ZHANG R,ZHU W X,ZHANG A,et al.Probabilistic design and reliability assessment methods for ablative thermal protection systems[J]. Chinese Journal of Computational Mechanics,2024,41(4):762-768.
[38]罗磊.C/SiC及其改性复合材料在等离子风洞中的烧蚀行为研究[D].西安:西北工业大学,2018:17-44.LUO L. Investigation on the ablation behaviors of C/SiC-based composites in plasma wind tunnel[D].Xi’an:Northwestern Polytechnical University,2018:17-44.
[39]李江,郭梦飞,刘洋,等.固体发动机绝热材料烧蚀研究进展[J].宇航学报,2019,40(10):1146-1157.LI J,GUO M F,LIU Y,et al.Review on ablation research of insulation materials for solid rocket motors[J]. Journal of Astronautics, 2019, 40(10):1146-1157.
[40]王金金,查柏林,张炜,等.多相流环境下绝热材料烧蚀试验方法研究[J].宇航学报,2019,40(3):362-368.WANG J J,ZHA B L,ZHANG W,et al.Experimental method research on ablation characteristics of thermal insulation material under multi-phase flow condition[J]. Journal of Astronautics, 2019,40(3):362-368.
[41]汪辰宇.抗激光烧蚀磷酸盐复合涂层研究[D].南京:南京航空航天大学,2023:5-53.WANG C Y. Research on phosphate composite coatings resistant to laser ablation[D]. Nanjing:Nanjing University of Aeronautics and Astronautics,2023:5-53.
[42]FELTRIN A C,AKHTAR F,HEDMAN D.Thermal properties and high-temperature ablation of highentropy(Ti0.25V0.25Zr0.25Hf0.25)B2coating on graphite substrate[J].Journal of Advanced Ceramics,2024,13(8):1268-1281.
[43]GUO L X,HUANG S W,LI W,et al.Theoretical design and experimental verification of highentropy carbide ablative resistant coating[J]. Advanced Powder Materials,2024,3(5):100213.
[44]DONG S M,NI D W,QIN Y Y,et al.Ablation behavior and mechanisms of Cf/(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C-SiC high-entropy ceramic matrix composites[J].Composites Part B,2022,243:110177.
[45]DONG S M,NI D W,CAI F Y,et al.Ablation mechanism of Cf/(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)CSiC composite during plasma ablation above 2 000℃[J]. Journal of Materials Science&Technology,2025,213:109-117.
[46]BIN HOQUE M S,MILICH M,AKHANDA M S,et al.Thermal and ablation properties of a highentropy metal diboride:(Hf0.2Zr0.2Ti0.2Ta0.2Nb0.2)B2[J]. Journal of the European Ceramic Society,2023,43(11):4581-4587.
[47]JIA X S,LUO J L,GUO C.High-energy continuous wave laser ablation of alumina ceramic[J].Journal of Materials Research and Technology,2023,27:5389-5403.
[48]WEN Z H,LIU Y W,YANG J,et al.Exceptional oxidation resistance of high-entropy carbides up to 3 600℃[J]. Advanced Materials, 2025, 37(34):e2507254.
[49]LV J,LI W,LI T,et al.Multicomponent(HfZr-Ta)B2coatings for carbon/carbon composites and structural optimization enabling superior ablation resistance[J]. Journal of Materials Science&Technology,2025,204(1):115-126.
[50]廖怡君,马艺,冀连泽,等.高熵合金纳米颗粒研究进展[J].中国科学:技术科学,2024, 54(7):1211-1245.LIAO Y J,MA Y,JI L Z,et al.Research advances in high-entropy alloy nanoparticles[J]. Scientia Sinica(Technologica),2024, 54(7):1211-1245.
[51]RAO Z Y,TUNG P Y,XIE R W,et al.Machine learning enabled high-entropy alloy discovery[J].Science,2022,378(6615):78-85.
[52]ZIATDIOV M,GHOSH A,WONG C Y T,et al.Atom AI framework for deep learning analysis of image and spectroscopy data in electron and scanning probe microscopy[J]. Nature Machine Intelligence,2022,4:1101-1112.
[53]LI H,ZHENG H B,YUE T L,et al.Machine learning-accelerated discovery of heat-resistant polysulfates for electrostatic energy storage[J]. Nature Energy,2025,10:90-100.
[54]SUZUKI Y,HINO H,HAWAI T,et al.Symmetry prediction and knowledge discovery from Xray diffraction patterns using an interpretable machine learning approach[J].Scientific Reports, 2020, 10(1):21790.
[55]FRIEDRICH R,CURTAROLO S.AFLOW-CCE for the thermodynamics of ionic materials[J].The Journal of Chemical Physics,2024,160:042501.
[56]ISAYE O,OSES C,TOHER C,et al.Universal fragment descriptors for predicting properties of inorganic crystals[J].Nature Communications,2017,8:15679.
[57]RACCUGLIA P, ELBERT K C, ADLER P D F,et al.Machine-learning-assisted materials discovery using failed experiments[J].Nature,2016,533(7601):73-76.
[58]DIVILOV S, ECKERT H, HICKS D, et al.Disordered enthalpy-entropy descriptor for high-entropy ceramics discovery[J]. Nature, 2024, 625(7993):66-73.
[59]黄中庆,彭爽,孙德恩,等.机器学习辅助设计高强韧(TiZrNbCrSi)N高熵氮化物涂层[J].表面技术,2025,54(1):74-83.HUANG Z Q,PENG S,SUN D E,et al.Machine learning assisted design of high hard yet tough(TiZrNbCrSi)N high-entropy nitride coatings[J].Surface Technology,2025,54(1):74-83.
[60]YANG S,GAO J,TRINI M,et al.Ni coarsening in Ni-yttria stabilized zirconia electrodes:threedimensional quantitative phase-field simulations supported by exsitu ptychographic nanotomography[J].Acta Materialia,2023,246:118708.
[61]MANDAL P, CHOUDHURY A, MALLICK A B, et al. Phase prediction in high entropy alloys by various machine learning modules using thermodynamic and configurational parameters[J]. Metals and Materials International,2023,29(1):38-52.
[62]GAO T,GAO J,ZHANG J,et al.Development of an accurate“composition-process-properties” dataset for SLMed Al-Si-(Mg)alloys and its application in alloy design[J]. Journal of Materials Informatics,2023,3(1):6.
[63]ZHANG Y J, ZHANG Z X, ZHANG X M, et al. Machine learning guided design and ablation behavior of ZrC-TaC-SiC ternary coatings[J]. Corrosion Science,2025,260:113499.
[64]SCHMIDT J, SHI J M, BORLIDO P, et al.Predicting the thermodynamic stability of solids combining density functional theory and machine learning[J]. Chemistry of Materials, 2018, 29:5090-5103.
[65]SHEN L, CHEN L, HUANG J, et al. Predicting phases and hardness of high entropy alloys based on machine learning[J].Intermetallics,2023,162:108030.
[66]刘娟,田传进,汪长安.基于机器学习设计和制备高熵氮化物陶瓷[J].硅酸盐学报.2023, 51(12):3095-3101.LIU J, TIAN C J, WANG C A. Design and preparation of high-entropy nitride ceramics via machine learning[J]. Journal of the Chinese Ceramic Society,2023,51(12):3095-3101.
[67]LI S L, LIU R, YAN H W, et al. Machine learning phase prediction of light-weight high-entropy alloys containing aluminum, magnesium, and lithium[J].Metals,2024,14:268951684.
[68]NASSAR A E, MULLIS A. Rapid screening of high-entropy alloys using neural networks and constituent elements[J]. Computational Materials Science,2021,199:110755.
[69]WANG Y X,LI Y,TANG Z C,et al.Universal materials model of deep-learning density functional theory Hamiltonian[J].Science Bulletin,2024,69(16):2514-2521.
[70]LUO Y X,SUN L C,WANG J M,et al.Elemental numerical descriptions to enhance classification and regression model performance for high-entropy alloys[J].NPJ Computational Materials,2025,11:75.
[71]LUO Y X, SUN L C, WANG J M, et al.Phase formation capability and compositional design of β-phase multiple rare-earth principal component disilicates[J].Nature Communications,2023,14(1):1275.
[72]MORTAZAVI B, SHOJAEI F, YAGMURCUKARDES M, et al. Anisotropic and outstanding mechanical,thermal conduction,optical,and piezoelectric responses in a novel semiconducting BCN monolayer confirmed by first-principles and machine learning[J].Carbon,2022,200:500-509.
[73]WANG L J, YANG T Y, FENG B, et al.Constructing dual electron transfer channels to accelerate CO2photoreduction guided by machine learning and first-principles calculation[J]. Chinese Journal of Catalysis,2023,54:265-277.
[74]WEN T, YE B L, LIU H H, et al. Formation criterion for binary metal diboride solid solutions established through combinatorial methods[J].Journal of the American Ceramic Society, 2020, 103:3338-3348.
[75]TAN Z Y,LIU Z Y,HU Y J,et al.Multiscale structural understanding of plasma spraying anti-ablation coating:an example of Ta-Hf-W-C ultrahigh temperature ceramics[J]. Corrosion Science,2024,234:112130.
[76]鲁楠,何鹏飞,种晓宇.多尺度模拟计算方法在超高温高熵陶瓷材料中的应用进展[J].宇航材料工艺,2023,53(1):1-12.LU N, HE P F, CHONG X Y. Application progress of multi-scale simulation method in ultrahigh-temperature high entropy ceramic materials[J].Aerospace Materials&Technology, 2023, 53(1):1-12.
[77]熊浩智,王云江.镍钴铬多主元合金高温高压相图与相变动力学模拟[J].物理学报,2025,74(8):7-19.XIONG H Z, WANG Y J. Kinetic simulation of phase diagram and phase transitions in NiCoCr multi-principal element alloy at high temperature and high pressure[J].Acta Physica Sinica,2025,74(8):7-19.
基本信息:
DOI:10.20189/j.cnki.CN/61-1527/E.202601004
中图分类号:V46
引用信息:
[1]李慧东,袁晓静,刘浩宇,等.耐烧蚀高熵涂层制备、评估与优化设计研究进展[J].火箭军工程大学学报,2026,40(01):32-45.DOI:10.20189/j.cnki.CN/61-1527/E.202601004.